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Journal Article

High-temperature self-energy corrections to x-ray absorption spectra

Effects of finite-temperature quasiparticle self-energy corrections on x-ray absorption spectra are investigated within the finite-temperature quasiparticle local density 𝐺⁢𝑊 approximation up to temperatures 𝑇 of order the Fermi temperature. To facilitate the calculations, we parametrize the quasiparticle self-energy using low-order polynomial fits. We show that temperature-driven decrease in the electron lifetime substantially broadens the spectra in the near-edge region with increasing 𝑇. However, the quasiparticle shift is most strongly modified near the onset of plasmon excitations.

Author(s)
Tun S. Tan
J. J. Kas
S. B. Trickey
J. J. Rehr
Journal Name
Phys. Rev. B
Publication Date
March 10, 2023
DOI
10.1103/PhysRevB.107.115122